Burnable Absorbers – Burnable Poisons

Burnable absorbers (also known as Burnable poisons) are materials that have a high neutron absorption cross-section that are converted into materials of relatively low absorption cross section as the result of radiative capture. Due to the burnup of the absorption material, the negative reactivity of the burnable absorber decreases over core life. Ideally, these absorbers should decrease their negative reactivity at the same rate the fuel’s excess positive reactivity is depleted. In PWRs burnable absorbers are used to decrease initial concentration of boric acid (also to decrease BOC MTC) and to decrease relative power of fresh fuel assemblies. Fixed burnable absorbers are generally used in the form of compounds of boron or gadolinium that are shaped into separate lattice pins or plates, or introduced as additives to the fuel. Since they can usually be distributed more uniformly than control rods, these poisons are less disruptive to the core power distribution.

  • Boron 10. Comparison of total cross-section and cross-section for (n,alpha) reactions.  Source: JANIS (Java-based Nuclear Data Information Software); The JEFF-3.1.1 Nuclear Data Library

    Boron 10. Comparison of total cross-section and cross-section for (n,alpha) reactions.
    Source: JANIS (Java-based Nuclear Data Information Software); The JEFF-3.1.1 Nuclear Data Library

    Boron as Burnable Absorber. In nuclear industry boron is commonly used as a neutron absorber due to the high neutron cross-section of isotope  10B. Its (n,alpha) reaction cross-section for thermal neutrons is about 3840 barns (for 0.025 eV neutron). Isotope  11B has absorption cross-section for thermal neutrons about 0.005 barns (for 0.025 eV neutron). Most of (n,alpha) reactions of thermal neutrons are 10B(n,alpha)7Li reactions accompanied by 0.48 MeV gamma emission(n,alpha) reactions of 10BMoreover, isotope 10B has high (n,alpha) reaction cross-section along the entire neutron energy spectrum. The cross-sections of most other elements becomes very small at high energies as in the case of cadmium. The cross-section of 10B decreases monotonically with energy. For fast neutrons its cross-section is on the order of barns. Boron as the neutron absorber has another positive property. The reaction products (after a neutron absorption), helium and lithium, are stable isotopes. Therefore there are minimal problems with decay heating of control rods or burnable absorbers used in the reactor core. On the other hand production of helium may lead to significant increase in pressure (under rod cladding), when used as the absorbing material in control rods. Moreover 10B is the principal source of radioactive tritium in primary circuit of all PWRs (which use boric acid as a chemical shim), because reactions with neutrons can rarely lead to formation of radioactive tritium via:

    • 10B(n,2x alpha)3H                             threshold reaction (~1.2 MeV)
    • 10B(n,alpha)7Li(n,n+alpha)3H     threshold reaction (~3 MeV).
  • Gadolinium 155 and 157. Comparison of radiative capture cross-sections.

    Gadolinium 155 and 157. Comparison of radiative capture cross-sections.
    Source: JANIS (Java-based Nuclear Data Information Software); The JEFF-3.1.1 Nuclear Data Library

    Gadolinium as Burnable Absorber. In nuclear industry gadolinium is commonly used as a neutron absorber due to very high neutron absorption cross-section of two isotopes 155Gd and 157Gd. In fact their absorption cross-sections are the highest among all stable isotopes. 155Gd has 61 000 barns for thermal neutrons (for 0.025 eV neutron) and 157Gd has even 254 000 barns. For this reason gadolinium is widely used as a burnable absorber, which is commonly used in fresh fuel to compensate an excess of reactivity of reactor core. In comparison with another burnable absorbers gadolinium behaves like a completely black material. Therefore gadolinium is very effective in compensation of the excess of reactivity, but on the other hand an improper distribution of Gd-burnable absorbers may lead to unevenness of neutron-flux density in the reactor core.

effect of gadolinium absorbers

The effect of gadolinium burnable absorbers (BA) can be demonstrated on boron letdown curves. At the beginning of specific fuel cycle the critical concentration of boric acid in the reactor core without burnable absorbers (blue curve) significantly differs from the critical concentration of boric acid in the reactor core with burnable absorbers (red curve). The difference is dependent on the amount of BA used.

Nuclear and Reactor Physics:

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Advanced Reactor Physics:

  1. K. O. Ott, W. A. Bezella, Introductory Nuclear Reactor Statics, American Nuclear Society, Revised edition (1989), 1989, ISBN: 0-894-48033-2.
  2. K. O. Ott, R. J. Neuhold, Introductory Nuclear Reactor Dynamics, American Nuclear Society, 1985, ISBN: 0-894-48029-4.
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  4. E. E. Lewis, W. F. Miller, Computational Methods of Neutron Transport, American Nuclear Society, 1993, ISBN: 0-894-48452-4.

See above: