# Silver – Specific Heat, Latent Heat of Fusion, Latent Heat of Vaporization

## Silver – Specific Heat, Latent Heat of Fusion, Latent Heat of Vaporization

Specific heat of Silver is 0.235 J/g K.

Latent Heat of Fusion of Silver is 11.3 kJ/mol.

Latent Heat of Vaporization of Silver is 250.58 kJ/mol.

Specific Heat

Specific heat, or specific heat capacity, is a property related to internal energy that is very important in thermodynamics. The intensive properties cv and cp are defined for pure, simple compressible substances as partial derivatives of the internal energy u(T, v) and enthalpy h(T, p), respectively:

where the subscripts v and p denote the variables held fixed during differentiation. The properties cv and cp are referred to as specific heats(or heat capacities) because under certain special conditions they relate the temperature change of a system to the amount of energy added by heat transfer. Their SI units are J/kg K or J/mol K.

Different substances are affected to different magnitudes by the addition of heat. When a given amount of heat is added to different substances, their temperatures increase by different amounts.

Heat capacity is an extensive property of matter, meaning it is proportional to the size of the system. Heat capacity C has the unit of energy per degree or energy per kelvin. When expressing the same phenomenon as an intensive property, the heat capacity is divided by the amount of substance, mass, or volume, thus the quantity is independent of the size or extent of the sample.

Latent Heat of Vaporization

In general, when a material changes phase from solid to liquid, or from liquid to gas a certain amount of energy is involved in this change of phase. In case of liquid to gas phase change, this amount of energy is known as the enthalpy of vaporization, (symbol ∆Hvap; unit: J) also known as the (latent) heat of vaporization or heat of evaporation. As an example, see the figure, which descibes phase transitions of water.

Latent heat is the amount of heat added to or removed from a substance to produce a change in phase. This energy breaks down the intermolecular attractive forces, and also must provide the energy necessary to expand the gas (the pΔV work). When latent heat is added, no temperature change occurs. The enthalpy of vaporization is a function of the pressure at which that transformation takes place.

Latent Heat of Fusion

In case of solid to liquid phase change, the change in enthalpy required to change its state is known as the enthalpy of fusion, (symbol ∆Hfus; unit: J) also known as the (latent) heat of fusion. Latent heat is the amount of heat added to or removed from a substance to produce a change in phase. This energy breaks down the intermolecular attractive forces, and also must provide the energy necessary to expand the system (the pΔV work).

The liquid phase has a higher internal energy than the solid phase. This means energy must be supplied to a solid in order to melt it and energy is released from a liquid when it freezes, because the molecules in the liquid experience weaker intermolecular forces and so have a higher potential energy (a kind of bond-dissociation energy for intermolecular forces).

The temperature at which the phase transition occurs is the melting point.

When latent heat is added, no temperature change occurs. The enthalpy of fusion is a function of the pressure at which that transformation takes place. By convention, the pressure is assumed to be 1 atm (101.325 kPa) unless otherwise specified.

## Silver – Properties

ElementSilver
Atomic Number47
SymbolAg
Element CategoryTransition Metal
Phase at STPSolid
Atomic Mass [amu]107.8682
Density at STP [g/cm3]10.49
Electron Configuration[Kr] 4d10 5s1
Possible Oxidation States+1
Electron Affinity [kJ/mol]125.6
Electronegativity [Pauling scale]1.93
1st Ionization Energy [eV]7.5762
Year of Discoveryunknown
Discovererunknown
Thermal properties
Melting Point [Celsius scale]961.78
Boiling Point [Celsius scale]2162
Thermal Conductivity [W/m K]430
Specific Heat [J/g K]0.235
Heat of Fusion [kJ/mol]11.3
Heat of Vaporization [kJ/mol]250.58

## Silver in Periodic Table

 Hydro­gen1H He­lium2He Lith­ium3Li Beryl­lium4Be Boron5B Carbon6C Nitro­gen7N Oxy­gen8O Fluor­ine9F Neon10Ne So­dium11Na Magne­sium12Mg Alumin­ium13Al Sili­con14Si Phos­phorus15P Sulfur16S Chlor­ine17Cl Argon18Ar Potas­sium19K Cal­cium20Ca Scan­dium21Sc Tita­nium22Ti Vana­dium23V Chrom­ium24Cr Manga­nese25Mn Iron26Fe Cobalt27Co Nickel28Ni Copper29Cu Zinc30Zn Gallium31Ga Germa­nium32Ge Arsenic33As Sele­nium34Se Bromine35Br Kryp­ton36Kr Rubid­ium37Rb Stront­ium38Sr Yttrium39Y Zirco­nium40Zr Nio­bium41Nb Molyb­denum42Mo Tech­netium43Tc Ruthe­nium44Ru Rho­dium45Rh Pallad­ium46Pd Silver47Ag Cad­mium48Cd Indium49In Tin50Sn Anti­mony51Sb Tellur­ium52Te Iodine53I Xenon54Xe Cae­sium55Cs Ba­rium56Ba Lan­thanum57La Haf­nium72Hf Tanta­lum73Ta Tung­sten74W Rhe­nium75Re Os­mium76Os Iridium77Ir Plat­inum78Pt Gold79Au Mer­cury80Hg Thallium81Tl Lead82Pb Bis­muth83Bi Polo­nium84Po Asta­tine85At Radon86Rn Fran­cium87Fr Ra­dium88Ra Actin­ium89Ac Ruther­fordium104Rf Dub­nium105Db Sea­borgium106Sg Bohr­ium107Bh Has­sium108Hs Meit­nerium109Mt Darm­stadtium110Ds Roent­genium111Rg Coper­nicium112Cn Nihon­ium113Nh Flerov­ium114Fl Moscov­ium115Mc Liver­morium116Lv Tenness­ine117Ts Oga­nesson118Og Cerium58Ce Praseo­dymium59Pr Neo­dymium60Nd Prome­thium61Pm Sama­rium62Sm Europ­ium63Eu Gadolin­ium64Gd Ter­bium65Tb Dyspro­sium66Dy Hol­mium67Ho Erbium68Er Thulium69Tm Ytter­bium70Yb Lute­tium71Lu Thor­ium90Th Protac­tinium91Pa Ura­nium92U Neptu­nium93Np Pluto­nium94Pu Ameri­cium95Am Curium96Cm Berkel­ium97Bk Califor­nium98Cf Einstei­nium99Es Fer­mium100Fm Mende­levium101Md Nobel­ium102No Lawren­cium103Lr