Supercritical Fluid – Supercritical Water
The classification of steam on wet, dry and superheated has its limitation. Consider the behavior of the system which is heated at the pressure, that is higher than the critical pressure. In this case, there would be no change in phase from liquid to steam. At all states there would be only one phase. Vaporization and condensation can occur only when the pressure is less than the critical pressure. The terms liquid and vapor tend to lose their significance.
At pressure, that is higher than the critical pressure, water is in special state, that is known as supercritical fluid state. A supercritical fluid is a fluid that is at pressures higher than its thermodynamic critical values. At the critical and supercritical pressures a fluid is considered as a single-phase substance in spite of the fact that all thermophysical properties undergo significant changes within the critical and pseudocritical regions.
See also: Critical Point of Water
At pressures above the critical pressure, properties of water in the reactor change gradually and continuously from those we ordinarily associate with a liquid (high density, small compressibility) to those of a gas (low density, large compressibility) without a phase change. There is no change in the phase of water in the core. On the other hand, physical properties such as density, specific heat, specific enthalpy undergo significant changes, especially in the temperature range of the pseudocritical region (for 25 MPa between 372°C and 392°C). For example, in a typical supercritical water reactor:
- the density of supercritical water at the inlet and at the outlet is about 777 kg/m3 (for 25MPa and 280°C) and 90 kg/m3 (for 25MPa and 500°C),
- the specific enthalpy of supercritical water at the inlet and at the outlet is about 1230 kJ/kg (for 25MPa and 280°C) and 3165 kJ/kg (for 25MPa and 500°C)
Following figures shows the behaviour of thermophysical properties of water near the critical (22.1MPa) and pseudocritical (25MPa) points. Near the critical point these property changes are dramatic. In the vicinity of the pseudocritical point at 25 MPa, these property changes become less significant. At 25 MPa the most significant property changes occur within ±25◦C around pseudocritical point (389.4◦C), this region is known as the pseudocritical region. For convenience, below the pseudocritical point fluid properties are considered to show liquid-like behaviour and above the pseudocritical point they are considered to show gas-like behaviour.