Pearlite

pearliteIn metallurgy, pearlite is a layered metallic structure of two-phases, which compose of alternating layers of ferrite (87.5 wt%) and cementite (12.5 wt%) that occurs in some steels and cast irons. It is named for its resemblance to mother of pearl. If steel (austenite) with a eutectoid composition of approximately 0.77% C is slowly cooled below 727 °C, the ferrite and cementite phase separate almost simultaneously to produce a microstructure with distinctive platelets. This distinctive microstructure of steel is called pearlite. A ferrite phase has a much lower carbon content, and cementite has a much higher carbon concentration.

In a hypereutectoid composition (greater than 0.8% carbon), the carbon will first precipitate out as large inclusions of cementite at the austenite grain boundaries until the percentage of carbon in the grains has decreased to the eutectoid composition (0.8% carbon), at which point the pearlite structure forms.

In a hypoeutectoid composition, that means when low-carbon steels (with up to 0.30% C) or medium-carbon steels (with 0.30 to 0.60% C) are slowly cooled from the austenitic phase, some low-carbon α-ferrite forms first along austenite grain boundaries) until the remaining composition rises to 0.8% of carbon, at which point the pearlite structure will form. No large inclusions of cementite will form at the boundaries in hypoeuctoid steel. The above assumes that the cooling process is very slow, allowing enough time for the carbon to migrate.

The most common structural steels produced have a mixed ferrite-pearlite microstructure. Their applications include beams for bridges and high-rise buildings, plates for ships, and reinforcing bars for roadways. These steels are relatively inexpensive and are produced in large tonnages.

Other Common Phases in Steels and Irons

Fe-Fe3C Phase Diagram
In the figure, there is the iron–iron carbide (Fe–Fe3C) phase diagram. The percentage of carbon present and the temperature define the phase of the iron carbon alloy and therefore its physical characteristics and mechanical properties. The percentage of carbon determines the type of the ferrous alloy: iron, steel or cast iron. Source: wikipedia.org Läpple, Volker – Wärmebehandlung des Stahls Grundlagen. License: CC BY-SA 4.0

Heat treatment of steels requires an understanding of both the equilibrium phases and the metastable phases that occur during heating and/or cooling. For steels, the stable equilibrium phases include:

  • Ferrite. Ferrite or α-ferrite is a body-centered cubic structure phase of iron which exists below temperatures of 912°C for low concentrations of carbon in iron. α-ferrite  can only dissolve up to 0.02 percent of carbon at 727°C. This is because of the configuration of the iron lattice which forms a BCC crystal structure. The primary phase of low-carbon or mild steel and most cast irons at room temperature is ferromagnetic α-Fe.
  • Austenite.  Austenite, also known as gamma-phase iron (γ-Fe), is a non-magnetic face-centered cubic structure phase of iron. Austenite in iron-carbon alloys is generally only present above the critical eutectoid temperature (723°C), and below 1500°C, depending on carbon content. However, it can be retained to room temperature by alloy additions such as nickel or manganese. Carbon plays an important role in heat treatment, because it expands the temperature range of austenite stability. Higher carbon content lowers the temperature needed to austenitize steel—such that iron atoms rearrange themselves to form an fcc lattice structure. Austenite is present in the most commonly used type of stainless steel, which are very well known for their corrosion resistance.
  • Graphite. Adding a small amount of non-metallic carbon to iron trades its great ductility for the greater strength.
  • CementiteCementite (Fe3C) is a metastable compound, and under some circumstances it can be made to dissociate or decompose to form α-ferrite and graphite, according to the reaction: Fe3C → 3Fe (α) + C (graphite). Cementite in its pure form is a ceramic and it is hard and brittle which makes it suitable for strengthening steels. Its mechanical properties are a function of its microstructure, which depends upon how it is mixed with ferrite.

The metastable phases are:

  • quenchingPearlite. In metallurgy, pearlite is a layered metallic structure of two-phases, which compose of alternating layers of ferrite (87.5 wt%) and cementite (12.5 wt%) that occurs in some steels and cast irons. It is named for its resemblance to mother of pearl.
  • Martensite. Martensite is a very hard metastable structure with a body-centered tetragonal (BCT) crystal structure. Martensite is formed in steels when the cooling rate from austenite is at such a high rate that carbon atoms do not have time to diffuse out of the crystal structure in large enough quantities to form cementite (Fe3C).
  • Bainite. Bainite is a plate-like microstructure that forms in steels from austenite when cooling rates are not rapid
    enough to produce martensite but are still fast enough so that carbon does not have enough time to diffuse to form pearlite. Bainitic steels are generally stronger and harder than pearlitic steels; yet they exhibit a desirable combination of strength and ductility.
References:
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U.S. Department of Energy, Material Science. DOE Fundamentals Handbook, Volume 2 and 2. January 1993.
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See above:
Phase Diagram