Tin Bronze

The bronzes are a family of copper-based alloys traditionally alloyed with tin, but can refer to alloys of copper and other elements (e.g. aluminum, silicon, and nickel). Bronzes are somewhat stronger than the brasses, yet they still have a high degree of corrosion resistance. Generally they are used when, in addition to corrosion resistance, good tensile properties are required. For example, beryllium copper attains the greatest strength (to 1,400 MPa) of any copper-based alloy.

Historically, alloying copper with another metal, for example tin to make bronze, was first practiced about 4000 years after the discovery of copper smelting, and about 2000 years after “natural bronze” had come into general use. An ancient civilization is defined to be in the Bronze Age either by producing bronze by smelting its own copper and alloying with tin, arsenic, or other metals. Bronze, or bronze-like alloys and mixtures, were used for coins over a longer period. Bronzes are still widely used today for springs, bearings, bushings, automobile transmission pilot bearings, and similar fittings, and is particularly common in the bearings of small electric motors. Brass and bronze are common engineering materials in modern architecture and primarily used for roofing and facade cladding due to their visual appearance.

Tin Bronzes

In general, bronzes are a family of copper-based alloys traditionally alloyed with tin, commonly with about 12–12.5% tin. The addition of small amounts (0.01–0.45) of phosphorus further increases the hardness, fatigue resistance and wear resistance. Addition of these alloyants leads to applications such as springs, fasteners, masonry fixings, shafts, valve spindles, gears and bearings. Bronze is also the preferred metal for bells in the form of a high tin bronze alloy known colloquially as bell metal, which is about 23% tin. High tin bronze alloys are typically found in also gears as well as high-strength bushing and bearing applications where high strength, and heavy loads are present. Other applications for these alloys are pump impellers, piston rings, and steam fittings. For example, copper casting alloy UNS C90500 is a cast alloy of copper-tin, which is also known as gun metal. Originally used chiefly for making guns, it has largely been replaced by steel.

bronze

Uses and Application of Bronzes

Historically, alloying copper with another metal, for example tin to make bronze, was first practiced about 4000 years after the discovery of copper smelting, and about 2000 years after “natural bronze” had come into general use. An ancient civilization is defined to be in the Bronze Age either by producing bronze by smelting its own copper and alloying with tin, arsenic, or other metals. The major applications of copper are electrical wire (60%), roofing and plumbing (20%), and industrial machinery (15%).

bronze bearing
Bronze bearing

Copper is used mostly as a pure metal, but when greater hardness is required, it is put into such alloys as brass and bronze (5% of total use). Copper and copper-based alloys including brasses (Cu-Zn) and bronzes (Cu-Sn) are widely used in different industrial and societal applications.  Some of the common uses for brass alloys include costume jewelry, locks, hinges, gears, bearings, ammunition casings, automotive radiators, musical instruments, electronic packaging, and coins. Bronze, or bronze-like alloys and mixtures, were used for coins over a longer period. is still widely used today for springs, bearings, bushings, automobile transmission pilot bearings, and similar fittings, and is particularly common in the bearings of small electric motors. Brass and bronze are common engineering materials in modern architecture and primarily used for roofing and facade cladding due to their visual appearance.

Properties of Tin Bronze

Material properties are intensive properties, that means they are independent of the amount of mass and may vary from place to place within the system at any moment. The basis of materials science involves studying the structure of materials, and relating them to their properties (mechanical, electrical etc.). Once a materials scientist knows about this structure-property correlation, they can then go on to study the relative performance of a material in a given application. The major determinants of the structure of a material and thus of its properties are its constituent chemical elements and the way in which it has been processed into its final form.

Mechanical Properties of Tin Bronze

Materials are frequently chosen for various applications because they have desirable combinations of mechanical characteristics. For structural applications, material properties are crucial and engineers must take them into account.

Strength of Tin Bronze

In mechanics of materials, the strength of a material is its ability to withstand an applied load without failure or plastic deformation. Strength of materials basically considers the relationship between the external loads applied to a material and the resulting deformation or change in material dimensions. Strength of a material is its ability to withstand this applied load without failure or plastic deformation.

Ultimate Tensile Strength

Ultimate tensile strength of tin bronze – UNS C90500 – gun metal is about 310 MPa.

Yield Strength - Ultimate Tensile Strength - Table of MaterialsThe ultimate tensile strength is the maximum on the engineering stress-strain curve. This corresponds to the maximum stress that can be sustained by a structure in tension. Ultimate tensile strength is often shortened to “tensile strength” or even to “the ultimate.”  If this stress is applied and maintained, fracture will result. Often, this value is significantly more than the yield stress (as much as 50 to 60 percent more than the yield for some types of metals). When a ductile material reaches its ultimate strength, it experiences necking where the cross-sectional area reduces locally. The stress-strain curve contains no higher stress than the ultimate strength. Even though deformations can continue to increase, the stress usually decreases after the ultimate strength has been achieved. It is an intensive property; therefore its value does not depend on the size of the test specimen. However, it is dependent on other factors, such as the preparation of the specimen, the presence or otherwise of surface defects, and the temperature of the test environment and material. Ultimate tensile strengths vary from 50 MPa for an aluminum to as high as 3000 MPa for very high-strength steels.

Yield Strength

Yield strength of tin bronze – UNS C90500 – gun metal is about 150 MPa.

The yield point is the point on a stress-strain curve that indicates the limit of elastic behavior and the beginning plastic behavior. Yield strength or yield stress is the material property defined as the stress at which a material begins to deform plastically whereas yield point is the point where nonlinear (elastic + plastic) deformation begins. Prior to the yield point, the material will deform elastically and will return to its original shape when the applied stress is removed. Once the yield point is passed, some fraction of the deformation will be permanent and non-reversible. Some steels and other materials exhibit a behaviour termed a yield point phenomenon. Yield strengths vary from 35 MPa for a low-strength aluminum to greater than 1400 MPa for very high-strength steels.

Young’s Modulus of Elasticity

Young’s modulus of elasticity of tin bronze – UNS C90500 – gun metal is about 103 GPa.

The Young’s modulus of elasticity is the elastic modulus for tensile and compressive stress in the linear elasticity regime of a uniaxial deformation and is usually assessed by tensile tests. Up to a limiting stress, a body will be able to recover its dimensions on removal of the load. The applied stresses cause the atoms in a crystal to move from their equilibrium position. All the atoms are displaced the same amount and still maintain their relative geometry. When the stresses are removed, all the atoms return to their original positions and no permanent deformation occurs. According to the Hooke’s law, the stress is proportional to the strain (in the elastic region), and the slope is Young’s modulus. Young’s modulus is equal to the longitudinal stress divided by the strain.

Hardness of Tin Bronze

Brinell hardness of tin bronze – UNS C90500 – gun metal is approximately 75 BHN.

Brinell hardness number

Rockwell hardness test is one of the most common indentation hardness tests, that has been developed for hardness testing. In contrast to Brinell test, the Rockwell tester measures the depth of penetration of an indenter under a large load (major load) compared to the penetration made by a preload (minor load). The minor load establishes the zero position. The major load is applied, then removed while still maintaining the minor load. The difference between depth of penetration before and after application of the major load is used to calculate the Rockwell hardness number. That is, the penetration depth and hardness are inversely proportional. The chief advantage of Rockwell hardness is its ability to display hardness values directly. The result is a dimensionless number noted as HRA, HRB, HRC, etc., where the last letter is the respective Rockwell scale.

The Rockwell C test is performed with a Brale penetrator (120°diamond cone) and a major load of 150kg.

Thermal Properties of Tin Bronze

Thermal properties of materials refer to the response of materials to changes in their temperature and to the application of heat. As a solid absorbs energy in the form of heat, its temperature rises and its dimensions increase. But different materials react to the application of heat differently.

Heat capacity, thermal expansion, and thermal conductivity are properties that are often critical in the practical use of solids.

Melting Point of Tin Bronze

Melting point of tin bronze – UNS C90500 – gun metal is around 1000°C.

In general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium.

Thermal Conductivity of Tin Bronze

The thermal conductivity of tin bronze – UNS C90500 – gun metal is 75 W/(m.K).

The heat transfer characteristics of a solid material are measured by a property called the thermal conductivity, k (or λ), measured in W/m.K. It is a measure of a substance’s ability to transfer heat through a material by conduction. Note that Fourier’s law applies for all matter, regardless of its state (solid, liquid, or gas), therefore, it is also defined for liquids and gases.

The thermal conductivity of most liquids and solids varies with temperature. For vapors, it also depends upon pressure. In general:

thermal conductivity - definition

Most materials are very nearly homogeneous, therefore we can usually write k = k (T). Similar definitions are associated with thermal conductivities in the y- and z-directions (ky, kz), but for an isotropic material the thermal conductivity is independent of the direction of transfer, kx = ky = kz = k.

References:
Materials Science:

U.S. Department of Energy, Material Science. DOE Fundamentals Handbook, Volume 1 and 2. January 1993.
U.S. Department of Energy, Material Science. DOE Fundamentals Handbook, Volume 2 and 2. January 1993.
William D. Callister, David G. Rethwisch. Materials Science and Engineering: An Introduction 9th Edition, Wiley; 9 edition (December 4, 2013), ISBN-13: 978-1118324578.
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Gaskell, David R. (1995). Introduction to the Thermodynamics of Materials (4th ed.). Taylor and Francis Publishing. ISBN 978-1-56032-992-3.
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See above:
Bronze