Radioactive Contamination

radioactive contamination
Radioactive contamination consist of radioactive material, that generate ionizing radiation. It is the source of radiation, not radiation itself.

Contamination is generally referred to as the presence of an unwanted constituent, harmful substance or impurity in a location (material, physical body, natural environment, workplace) where it is not intended or desired to be. Contamination has much more general meaning, since is can be defined in disciplines such as chemistry, environmental protection, radiation protection or agriculture.

Radioactive contamination is referred to as the presence of an unwanted radioactive substances on surfaces, or within solids (including the human body), liquids or gases, where their presence is unintended or undesirable. Radioactive contamination consist of radioactive atoms (material) that have escaped the system or structure that would normally contain them. Since radioactive contamination is radioactive material, ionizing radiation is emitted by the contamination. It is very important, which material (which radioisotope) is the radioactive contaminant. It is also very important to distinguish between radioactive contamination and radiation itself.

Contamination versus Radiation

Radioactive contamination consist of radioactive material, that generate ionizing radiation. It is the source of radiation, not radiation itself. Anytime that radioactive material is not in a sealed radioactive source container and might be spread onto other objects, radioactive contamination is a possibility. Radioactive contamination may be characterized by following points:

  • Radioactive contamination consist of radioactive material (contaminants), that may be solid, liquid or gaseous. Large contaminants can be even visible, but you cannot see radiation produced.
  • When released, contaminants can be spread by air, water or just by mechanical contact.
  • We cannot shield contamination.
  • We can mitigate contamination by protecting integrity of barriers (source container, fuel cladding, reactor vessel, containment building)
  • Since contaminants interact chemically, they may be contained within objects such as the human body.
  • We can rid of contamination by many mechanical, chemical (decontaminate surfaces), or biological processes (biological half-life).
  • It is of the highest importance, which material is the radioactive contaminant (half-life, mode of decay, energy).

Ionizing radiation is formed by high-energy particles (photons, electrons, etc.), that can penetrate matter and ionize (to form ion by losing electrons) target atoms to form ions. Radiation exposure is the consequence of the presence nearby the source of radiation. Radiation exposure as a quantity is defined as a measure of the ionization of material due to ionizing radiation. The danger of ionizing radiation lies in the fact that the radiation is invisible and not directly detectable by human senses. People can neither see nor feel radiation, yet it deposits energy to the molecules of the body. The energy is transferred in small quantities for each interaction between radiation and a molecule and there are usually many such interactions. Unlike radioactive contamination, radiation may be characterized by following points:

  • Radiation consist consist of high-energy particles that can penetrate matter and ionize (to form ion by losing electrons) target atoms. Radiation is invisible, and not directly detectable by human senses. It must be noted, beta radiation is indirectly visible due to cherenkov radiation.
  • Unlike contamination, radiation cannot be spread by any medium. It travels through materials until it loses its energy. We can shield radiation (e.g. by standing around the corner).
  • Exposure to ionizing does not necessary mean, that the object becomes radioactive (except very rare neutron radiation).
  • Radiation can penetrate barriers, but sufficiently thick barrier can minimize all effects.
  • Unlike contaminants, radiation cannot interact chemically with matter and cannot be bound inside body.
  • It is not important, which material is the source of certain radiation. Only type of radiation and energy matters.

There is one common feature, natural radiation and natural contaminants are all around us. In, around, and above the world we live in. It is a natural energy force that surrounds us. It is a part of our natural world that has been here since the birth of our planet. All living creatures, from the beginning of time, have been, and are still being, exposed to ionizing radiation. Natural background radiation is ionizing radiation, that originates from a variety of natural sources. All living creatures, from the beginning of time, have been, and are still being, exposed to ionizing radiation. This radiation is not associated with any human activity.  There are radioactive isotopes in our bodies, houses, air, water and in the soil. We all are also exposed to radiation from outer space.

Types of Contamination

Radioactive materials may exist on surfaces or in volumes of material or air, and specialist techniques are used to measure the levels of contamination by detection of the emitted radiation. We can distinguish between following types of contamination:

Surface Contamination

Surface contamination means that radioactive material has been deposited on surfaces (such as walls, floors). It may be loosely deposited, much like ordinary dust, or it may be quite firmly fixed by chemical reaction. This distinction is important, and we classify surface contamination on the basis of how easily it can be removed:

  • Free Contamination. In the case of free contamination (or loose contamination), the radioactive material can be spread. This is surface contamination that can easily be removed with simple decontamination methods. For example, if dust particles containing various radioisotopes land on the person’s skin or garments, we can clean it up or remove clothes. Once a person has been decontaminated, all of the particulate radioactivity sources are eliminated, and the individual is no longer contaminated. Free contamination is also a more serious hazard than fixed contamination, because dust particles can become airborne and they can be easily ingested. This leads to an internal exposure by radioactive contaminants. Although almost all contaminants are beta radioactive with accompanying gamma emission, but there is also the possibility of alpha contamination in any nuclear fuel handling areas.
  • Fixed Contamination. In the case of fixed contamination, the radioactive material cannot be spread, since it is chemically or mechanically bound to structures. It cannot be removed by normal cleaning methods. Fixed contamination is a less serious hazard than free contamination, it cannot be re-suspended or transferred to skin. Therefore the hazard is usually an external one only. On the other hand, it depends on the level of contamination. Although almost all contaminants are beta radioactive with accompanying gamma emission, but there is also the possibility of alpha contamination in any nuclear fuel handling areas. Unless the level of contamination is very severe, the gamma radiation dose rate will be small and external exposure will be significant only in contact with, or very close to, the contaminated surfaces. Since beta particles are less penetrating than gamma rays, the beta dose rate can be high only at contact. A value of 1 mSv/h at contact for a contamination level of 400 – 500 Bq/cm2 is fairly representative.
Calculation of Shielded Dose Rate in Sieverts from Contaminated Surface

Assume a surface, which is contamined by 1.0 Ci of 137Cs. Assume that this contaminant can be aproximated by the point isotropic source which contains 1.0 Ci of 137Cs, which has a half-life of 30.2 years. Note that the relationship between half-life and the amount of a radionuclide required to give an activity of one curie is shown below. This amount of material can be calculated using λ, which is the decay constant of certain nuclide:

Curie - Unit of Activity

About 94.6 percent decays by beta emission to a metastable nuclear isomer of barium: barium-137m. The main photon peak of Ba-137m is 662 keV. For this calculation, assume that all decays go through this channel.

Calculate the primary photon dose rate, in sieverts per hour (Sv.h-1), at the outer surface of a 5 cm thick lead shield. Then calculate the equivalent and effective dose rates for two cases.

  1. Assume that this external radiation field penetrates uniformly through the whole body. That means: Calculate the effective whole-body dose rate.
  2. Assume that this external radiation field penetrates only lungs and the other organs are completely shielded. That means: Calculate the effective dose rate.

Note that, primary photon dose rate neglects all secondary particles. Assume that the effective distance of the source from the dose point is 10 cm. We shall also assume that the dose point is soft tissue and it can reasonably be simulated by water and we use the mass energy absorption coefficient for water.

See also: Gamma Ray Attenuation

See also: Shielding of Gamma Rays

Solution:

The primary photon dose rate is attenuated exponentially, and the dose rate from primary photons, taking account of the shield, is given by:

dose rate calculation

As can be seen, we do not account for the buildup of secondary radiation. If secondary particles are produced or if the primary radiation changes its energy or direction, then the effective attenuation will be much less.  This assumption generally underestimates the true dose rate, especially for thick shields and when the dose point is close to the shield surface, but this assumption simplifies all calculations. For this case the true dose rate (with the buildup of secondary radiation) will be more than two times higher.

To calculate the absorbed dose rate, we have to use in the formula:

  • k = 5.76 x 10-7
  • S = 3.7 x 1010 s-1
  • E = 0.662 MeV
  • μt/ρ =  0.0326 cm2/g (values are available at NIST)
  • μ =  1.289 cm-1 (values are available at NIST)
  • D = 5 cm
  • r = 10 cm

Result:

The resulting absorbed dose rate in grays per hour is then:

absorbed dose rate - gray - calculation

1) Uniform irradiation

Since the radiation weighting factor for gamma rays is equal to one and we have assumed the uniform radiation field (the tissue weighting factor is also equal to unity), we can directly calculate the equivalent dose rate and the effective dose rate (E = HT) from the absorbed dose rate as:

calculation - effective dose - uniform

2) Partial irradiation

In this case we assume a partial irradiation of lungs only. Thus, we have to use the tissue weighting factor, which is equal to wT = 0.12. The radiation weighting factor for gamma rays is equal to one. As a result, we can calculate the effective dose rate as:

calculation - effective dose - non-uniform

Note that, if one part of the body (e.g.,the lungs) receives a radiation dose, it represents a risk for a particularly damaging effect (e.g., lung cancer). If the same dose is given to another organ it represents a different risk factor.

If we want to account for the buildup of secondary radiation, then we have to include the buildup factor. The extended formula for the dose rate is then:

absorbed dose rate - gray

 

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Airborne Contamination

This type of contamination is of particular importance in nuclear power plants, where it must be monitored. Contaminants can become airborne especially during reactor top head remove, reactor refueling, and during manipulations within spent fuel pool. The air can be contaminated with radioactive isotopes especially in particulate form, which poses a particular inhalation hazard. This contamination consists of various fission and activation products that enter the air in gaseous, vapour or particulate form. There are four types of airborne contamination in nuclear power plants, namely:

  • Particulates. Particulate activity is an internal hazard, because it can be inhaled. Transportable particulate material taken into the respiratory system will enter the blood stream and be carried to all parts of the body. Non-transportable particulates will stay in the lungs with a certain biological half-life. For example, Sr-90, Ra-226 and Pu-239 are radionuclides known as bone-seeking radionuclides. These radionuclides have long biological half-lives and are serious internal hazards. Once deposited in bone, they remain there essentially unchanged in amount during the lifetime of the individual. The continued action of the emitted alpha particles can cause significant injury: over many years they deposit all their energy in a tiny volume of tissue, because the range of the alpha particles is very short.
  • Noble gases. Radioactive noble gases, such as xenon-133, xenon-135 and  krypton-85 are present in reactor coolant especially when fuel leakages are present. As they appear in coolant, they become airborne and they can be inhaled. They are exhaled right after they are inhaled, because the body does not react chemically with them. If workers are working in a noble gas cloud, the external dose they will receive is about 1000 times greater than the internal dose. Because of this, we are only concerned about the external beta and gamma dose rates.
  • Iodine 131 - decay schemeRadioiodine. Radioiodine, iodine-131, is an important radioisotope of iodine. Radioiodine plays a major role as a radioactive isotope present in nuclear fission products, and it is a major contributor to the health hazards when released into the atmosphere during an accident. Iodine-131 has a half-life of 8.02 days. The target tissue for radioiodine exposure is the thyroid gland. The external beta and gamma dose from radioiodine present in the air is quite negligible when compared to the committed dose to the thyroid that would result from breathing this air. The biological half-life for iodine inside the human body is about 80 days (according to ICRP). Iodine in food is absorbed by the body and preferentially concentrated in the thyroid where it is needed for the functioning of that gland. When 131I is present in high levels in the environment from radioactive fallout, it can be absorbed through contaminated food, and will also accumulate in the thyroid. 131I decays with a half-life of 8.02 days with beta particle and gamma emissions. As it decays, it may cause damage to the thyroid. The primary risk from exposure to high levels of 131I is the chance occurrence of radiogenic thyroid cancer in later life. For 131I, ICRP has calculated that if you inhale 1 x 106 Bq, you will receive a thyroid dose of HT = 400 mSv (and weighted whole-body dose of 20 mSv).
  • Tritium. Tritium is a byproduct in nuclear reactors. Most important source (due to releases of tritiated water) of tritium in nuclear power plants stems from the boric acid, which is commonly used as a chemical shim to compensate an excess of initial reactivity. Note that, tritium emits low-energy beta particles with a short range in body tissues and, therefore, poses a risk to health as a result of internal exposure only following ingestion in drinking water or food, or inhalation or absorption through the skin. The tritium taken into the body is uniformly distributed among all soft tissues. According to the ICRP, a biological half-time of tritium is 10 days for HTO and 40 days for OBT (organically bound tritium) formed from HTO in the body of adults. As a result, for an intake of 1 x 109 Bq of tritium (HTO), an individual will get a whole-body dose of 20 mSv (equal to the intake of 1 x 106 Bq of 131I). While for PWRs tritium poses a minor risk to health, for heavy water reactors, it contributes significantly to collective dose of plant workers. Note that, “Air that is saturated with moderator water at 35°C can give 3 000 mSv/h of tritium to an unprotected worker (See also: J.U.Burnham. Radiation Protection). The best protection from tritium can be achieved using an air-supplied respirator. Tritium cartridge respirators protects workers only by a factor of 3. The only way to reduce the skin absorption is by wearing plastics. In PHWR power plants, workers must wear plastics for work in atmospheres containing more than 500 μSv/h.

Respirators with suitable air filters, or completely self-contained suits with their own air supply can mitigate dangers from airborne contamination. Airborne contamination is usually measured by special radiological instruments that continuously pump the sampled air through a filter. Instruments that do this are called Continuous Air Monitors (CAM). Radioactive particulates in the air collect on the filter, where the activity is measured by a detector placed close to the filter.

See also: Derived Air Concentration

See also: Annual Limit on Intake

Decontamination

Decontamination is a process used to reduce, or remove radioactive contamination to reduce the risk of radiation exposure. The removal of contamination from occupied areas, equipment and personnel is important to maintain an ionizing radiation dose as low as reasonably achievable (ALARA). Decontamination also reduces background radiation levels, radioactive material inventory, and the spread of contamination to uncontrolled areas, equipment and personnel.

Decontamination may be accomplished by cleaning or treating surfaces to reduce or remove the contamination. It may be also accomplished by filtering contaminated air or water or by covering the contamination to shield or absorb the radiation. The process can also simply allow adequate time for natural radioactive decay to decrease the radioactivity.

In nuclear power plants, it is inevitable that many items of equipment, and also tools, clothing, work areas, and even people will become contaminated. This is quite common, that some of radioactive material becomes attached to surfaces (e.g. the sole of a shoe). In this case, workers are continuously monitored and in this case, surface contamination must be removed. We can rid of contamination by many mechanical, chemical (decontaminate surfaces). Biological processes (biological half-life) always work in case of internal contamination. A person becomes ‘radioactive’ if dust particles containing various radioisotopes land on the person’s skin or garments. Once a person has been decontaminated by clothes removal and dermal scrubbing, all of the particulate radioactivity sources are eliminated, and the individual is no longer contaminated.

Decontamination Techniques

In general, there are many techniques and equipment used for decontamination surfaces and persons. In any case, type of contamination and contaminated material matters. For example, it is very difficult to decontaminate porous materials. As a general orientation to the reader, these decontamination techniques and their main applications are highlighted in:

Special Reference: State of the Art Technology for Decontamination and Dismantling of Nuclear Facilities, IAEA. IAEA Vienna, 1999. ISBN 92–0–102499–1.

  • Chemical Decontamination. Chemical decontamination is one of the best method for most decontamination operations is to clean with water to which one or more suitable chemical cleaning agents have been added. These methods include decontamination using chemical solutions, chemical gels, foam decontamination etc. Removing contamination from personnel must be done carefully to ensure the skin is not damaged, and to prevent contamination from entering the body or a wound.
  • Mechanical Decontamination. Mechanical decontamination can be used especially for industrial decontamination. There are decontamination methods in which the outer layer of the contaminated surface is removed by physical force. Such methods are effective, but they are somewhat crude and destructive, and it may not be possible to use them on delicate objects. These methods include decontamination using steam cleaning, abrasive cleaning, sandblasting, vacuum cleaning, ultrasonic cleaning etc.
References:

Radiation Protection:

  1. Knoll, Glenn F., Radiation Detection and Measurement 4th Edition, Wiley, 8/2010. ISBN-13: 978-0470131480.
  2. Stabin, Michael G., Radiation Protection and Dosimetry: An Introduction to Health Physics, Springer, 10/2010. ISBN-13: 978-1441923912.
  3. Martin, James E., Physics for Radiation Protection 3rd Edition, Wiley-VCH, 4/2013. ISBN-13: 978-3527411764.
  4. U.S.NRC, NUCLEAR REACTOR CONCEPTS
  5. U.S. Department of Energy, Nuclear Physics and Reactor Theory. DOE Fundamentals Handbook, Volume 1 and 2. January 1993.

Nuclear and Reactor Physics:

  1. J. R. Lamarsh, Introduction to Nuclear Reactor Theory, 2nd ed., Addison-Wesley, Reading, MA (1983).
  2. J. R. Lamarsh, A. J. Baratta, Introduction to Nuclear Engineering, 3d ed., Prentice-Hall, 2001, ISBN: 0-201-82498-1.
  3. W. M. Stacey, Nuclear Reactor Physics, John Wiley & Sons, 2001, ISBN: 0- 471-39127-1.
  4. Glasstone, Sesonske. Nuclear Reactor Engineering: Reactor Systems Engineering, Springer; 4th edition, 1994, ISBN: 978-0412985317
  5. W.S.C. Williams. Nuclear and Particle Physics. Clarendon Press; 1 edition, 1991, ISBN: 978-0198520467
  6. G.R.Keepin. Physics of Nuclear Kinetics. Addison-Wesley Pub. Co; 1st edition, 1965
  7. Robert Reed Burn, Introduction to Nuclear Reactor Operation, 1988.
  8. U.S. Department of Energy, Nuclear Physics and Reactor Theory. DOE Fundamentals Handbook, Volume 1 and 2. January 1993.
  9. Paul Reuss, Neutron Physics. EDP Sciences, 2008. ISBN: 978-2759800414.

See above:

Protection from Exposures