Joule’s Second Law

Joule’s Second Law

For any gas whose equation of state is given exactly by pV = nRT (or pv = RT), the specific internal energy depends on temperature only. This rule was originally found in 1843 by an English physicist James Prescott Joule experimentally for real gases and is known as Joule’s second law:

The internal energy of a fixed mass of an ideal gas depends only on its temperature (not pressure or volume).

The specific enthalpy of a gas described by pV = nRT also depends on temperature only. Note that, the enthalpy is the thermodynamic quantity equivalent to the total heat content of a system. It is equal to the internal energy of the system plus the product of pressure and volume. In intensive variables the Joule’s second law is therefore given by h = h(T) = u(T) + pv = u(T) + RT.

These three equations constitute the ideal gas model, summarized as follows:

pv = RT

u = u(T)

h = h(T) = u(T) + RT

 
References:
Reactor Physics and Thermal Hydraulics:
  1. J. R. Lamarsh, Introduction to Nuclear Reactor Theory, 2nd ed., Addison-Wesley, Reading, MA (1983).
  2. J. R. Lamarsh, A. J. Baratta, Introduction to Nuclear Engineering, 3d ed., Prentice-Hall, 2001, ISBN: 0-201-82498-1.
  3. W. M. Stacey, Nuclear Reactor Physics, John Wiley & Sons, 2001, ISBN: 0- 471-39127-1.
  4. Glasstone, Sesonske. Nuclear Reactor Engineering: Reactor Systems Engineering, Springer; 4th edition, 1994, ISBN: 978-0412985317
  5. Todreas Neil E., Kazimi Mujid S. Nuclear Systems Volume I: Thermal Hydraulic Fundamentals, Second Edition. CRC Press; 2 edition, 2012, ISBN: 978-0415802871
  6. Zohuri B., McDaniel P. Thermodynamics in Nuclear Power Plant Systems. Springer; 2015, ISBN: 978-3-319-13419-2
  7. Moran Michal J., Shapiro Howard N. Fundamentals of Engineering Thermodynamics, Fifth Edition, John Wiley & Sons, 2006, ISBN: 978-0-470-03037-0
  8. Kleinstreuer C. Modern Fluid Dynamics. Springer, 2010, ISBN 978-1-4020-8670-0.
  9. U.S. Department of Energy, THERMODYNAMICS, HEAT TRANSFER, AND FLUID FLOW. DOE Fundamentals Handbook, Volume 1, 2 and 3. June 1992.

See above:

Ideal Gas Law