Uranium Milling

nuclear fuel cycle
Nuclear Fuel Cycle. Source: Nuclear Regulatory Commission from US. License: CC BY 2.0

Uranium milling is a series of mechanical and chemical processes, which processes extracted uranium ore and produces dry powder-form material consisting of natural uranium, which is called “yellowcake” (chemically U3O8)  because of its yellowish color. Uranium ores are normally processed by grinding the ore materials to a uniform particle size and then treating the ore to extract the uranium by chemical leaching.

A conventional uranium mill is a chemical plant, usually built near the uranium mine. Uranium milling extracts uranium using the following process:

  • Milling. Trucks deliver uranium ore to the mill, where it is crushed into smaller particles before being extracted (or leached). Due to the very low concentration of uranium in the rock, immense amounts of rock have to be moved and processed in order to get a few kilograms of natural uranium. This results in enormous heaps. Due to high amounts of material, milling is generally carried out close to a uranium mine.
  • Leaching. After milling, a fine slurry is leached in sulfuric acid (or sometimes a strong alkaline solution) to allow the separation of uranium from the waste rock. It is then recovered from solution and precipitated as uranium oxide (U3O8) concentrate. After drying and usually heating a yellow-brownish powder, yellowcake,  is packed in 200-litre drums as a concentrate. In addition to extracting 90 to 95 percent of the uranium from the ore, the leaching agent also extracts several other “heavy metal” constituents, including molybdenum, vanadium, selenium, iron, lead, and arsenic.)
  • Further processing. Yellowcake is then refined to obtain almost pure uranium in the form of triuranium octoxide (U3O8). Pure U3O8 is then used in the preparation of uranium fuel for nuclear reactors, for which triuranium octoxide powder may be sintered into fuel pellets (UO2) for use in fuel rods for pressurized heavy-water reactors. For other systems that use enriched uranium, uranium conversion and enrichment must follow this process.

The remainder of the ore, containing most of the radioactivity and nearly all the rock material, becomes uranium tailings, which are emplaced in engineered facilities near the mine (often in a mined out pit). It must be noted, uranium tailings contains almost all the descendants of radioactive cascades, that have been in radioactive equilibrium for millions of years. For example, pure uranium-238, from uranium series, is weakly radioactive (proportional to its long half-life), but a uranium ore is about 13 times more radioactive than the pure uranium-238 metal because of its daughter isotopes (e.g. radon, radium etc.) it contains. Not only are unstable radium isotopes significant radioactivity emitters, but as the next stage in the decay chain they also generate radon, a heavy, inert, naturally occurring radioactive gas. At this place, we are discussing natural facts, it must be noted, the decay heat of uranium and its decay products (e.g. radon, radium etc.) contributes to heating of Earth’s core. Together with thorium and potassium-40 in the Earth’s mantle is thought that these elements are the main source of heat that keeps the Earth’s core liquid. But uranium tailings need to be isolated from the environment because they are concentrated and they contain these long-lived radioactive materials from radioactive decay chain.

Consumption of a 3000MWth (~1000MWe) pressurized water reactor (12-months fuel cycle)

It is an illustrative example, following data do not correspond to any reactor design.

  • Typical reactor may contain about 100 tonnes of enriched uranium (i.e. about 113 tonnes of uranium dioxide).
  • This fuel is loaded within, for example, 157 fuel assemblies composed of over 45,000 fuel rods.
  • A common fuel assembly contain energy for approximately 4 years of operation at full power.
  • Therefore about one quarter of the core is yearly removed to spent fuel pool (i.e. about 40 fuel assemblies), while the remainder is rearranged to a location in the core better suited to its remaining level of enrichment (see Power Distribution).

Annual natural uranium consumption of this reactor is about 250 tonnes of natural uranium (to produce of about 25 tonnes of enriched uranium).

References:
Nuclear and Reactor Physics:
      1. J. R. Lamarsh, Introduction to Nuclear Reactor Theory, 2nd ed., Addison-Wesley, Reading, MA (1983).
      2. J. R. Lamarsh, A. J. Baratta, Introduction to Nuclear Engineering, 3d ed., Prentice-Hall, 2001, ISBN: 0-201-82498-1.
      3. W. M. Stacey, Nuclear Reactor Physics, John Wiley & Sons, 2001, ISBN: 0- 471-39127-1.
      4. Glasstone, Sesonske. Nuclear Reactor Engineering: Reactor Systems Engineering, Springer; 4th edition, 1994, ISBN: 978-0412985317
      5. W.S.C. Williams. Nuclear and Particle Physics. Clarendon Press; 1 edition, 1991, ISBN: 978-0198520467
      6. G.R.Keepin. Physics of Nuclear Kinetics. Addison-Wesley Pub. Co; 1st edition, 1965
      7. Robert Reed Burn, Introduction to Nuclear Reactor Operation, 1988.
      8. U.S. Department of Energy, Nuclear Physics and Reactor Theory. DOE Fundamentals Handbook, Volume 1 and 2. January 1993.

Advanced Reactor Physics:

      1. K. O. Ott, W. A. Bezella, Introductory Nuclear Reactor Statics, American Nuclear Society, Revised edition (1989), 1989, ISBN: 0-894-48033-2.
      2. K. O. Ott, R. J. Neuhold, Introductory Nuclear Reactor Dynamics, American Nuclear Society, 1985, ISBN: 0-894-48029-4.
      3. D. L. Hetrick, Dynamics of Nuclear Reactors, American Nuclear Society, 1993, ISBN: 0-894-48453-2. 
      4. E. E. Lewis, W. F. Miller, Computational Methods of Neutron Transport, American Nuclear Society, 1993, ISBN: 0-894-48452-4.

See above:

Nuclear Fuel Cycle