Rhodium-104 as Emitter – Rhodium-103 as Material

self-powered neutron detector - incore instrumentationOne of possible materials is rhodium as the emitter. A SPND with a rhodium emitter has a relatively high sensitivity, high burn-up rate, perturbs the local power density and has a (two-fold) delayed signal. Rhodium-based detector is the beta-current type of self-powered detector, which uses the following activation reaction to produce a current that can be measured.

1n + 103Rh → 104Rh → 104Pd + β

As can be seen, a neutron captured by rhodium-103 causes a rhodium-103 atom to become a radioactive rhodium-104 atom. The rhodium-104 then decays into palladium-104 plus a beta particle (electron). The beta particle has enough energy to pass through the insulator and reach the collector. The half-life of activated rhodium-104 is 42.3 seconds, which delays the emission of the charged particle. Rhodium based detector uses this production of beta particles (electrons) to create a current that is proportional to the number of neutrons captured by the emitter, which is also proportional to local reactor power density. A portion of the detector’s current flow is due to gamma rays. In order to compensate for this erroneous signal, a background correction is performed via background detector, which consists of the same components as the detector, except the rhodium is removed.

Rhodium-103 has a capture cross-section of 133 barns for thermal neutrons and a resonance at 1.25 eV. This reaction leads to production of 104Rh with T1/2 = 42 sec which is beta radioactive. It must be noted about 11 barns belong to reaction in which an isomer 104mRh is produced (with T1/2 = 4.4 min).

The following characteristics are typical when used in thermal power reactor (e.g. PWR).

  • The rhodium burnup rate is 0.39% per month in a thermal neutron flux of 1013n/cm2/sec.
  • 92% of the signal has a half-life of 42 seconds.
  • 8% of the signal has a half-life of 4.4 minutes.
  • The beta emission has an energy of 2.44 MeV.
References:

Radiation Protection:

  1. Knoll, Glenn F., Radiation Detection and Measurement 4th Edition, Wiley, 8/2010. ISBN-13: 978-0470131480.
  2. Stabin, Michael G., Radiation Protection and Dosimetry: An Introduction to Health Physics, Springer, 10/2010. ISBN-13: 978-1441923912.
  3. Martin, James E., Physics for Radiation Protection 3rd Edition, Wiley-VCH, 4/2013. ISBN-13: 978-3527411764.
  4. U.S.NRC, NUCLEAR REACTOR CONCEPTS
  5. U.S. Department of Energy, Instrumantation and Control. DOE Fundamentals Handbook, Volume 2 of 2. June 1992.

Nuclear and Reactor Physics:

  1. J. R. Lamarsh, Introduction to Nuclear Reactor Theory, 2nd ed., Addison-Wesley, Reading, MA (1983).
  2. J. R. Lamarsh, A. J. Baratta, Introduction to Nuclear Engineering, 3d ed., Prentice-Hall, 2001, ISBN: 0-201-82498-1.
  3. W. M. Stacey, Nuclear Reactor Physics, John Wiley & Sons, 2001, ISBN: 0- 471-39127-1.
  4. Glasstone, Sesonske. Nuclear Reactor Engineering: Reactor Systems Engineering, Springer; 4th edition, 1994, ISBN: 978-0412985317
  5. W.S.C. Williams. Nuclear and Particle Physics. Clarendon Press; 1 edition, 1991, ISBN: 978-0198520467
  6. G.R.Keepin. Physics of Nuclear Kinetics. Addison-Wesley Pub. Co; 1st edition, 1965
  7. Robert Reed Burn, Introduction to Nuclear Reactor Operation, 1988.
  8. U.S. Department of Energy, Nuclear Physics and Reactor Theory. DOE Fundamentals Handbook, Volume 1 and 2. January 1993.
  9. Paul Reuss, Neutron Physics. EDP Sciences, 2008. ISBN: 978-2759800414.

See above:

Incore Instrumentation