# Characteristics of Thorium Reactor – Properties of Thorium

## Characteristics of Thorium Reactor

Thorium reactors are based on the thorium fuel cycle and use thorium 232 as a fertile material. During the fuel burning, thorium 232 transforms into a fissile  uranium 233. Unlike natural uranium, natural thorium contains only trace amounts of fissile material (such as thorium 231), which are insufficient to initiate and sustain nuclear chain reaction. Therefore, additional fissile material is necessary to initiate the fuel cycle.

According to proponents, the thorium fuel cycle offers several potential advantages over a uranium fuel cycle, including thorium’s greater abundance, better physical and nuclear properties (e.g. lower capture-to-fission ratio for thermal neutrons), reduced plutonium and actinide production, and better resistance to nuclear weapons proliferation when used in traditional light water reactors.

On the other hand, thorium is “only” a fertile material and the main problem can be directly in the breeding of fissile uranium 233. If 232Th is loaded in the nuclear reactor, the nuclei of 232Th absorb a neutron and become nuclei of 233Th. The half-life of 233Th is approximately 21.8 minutes. 233Th decays (negative beta decay) to 233Pa (protactinium), whose half-life is 26.97 days. 233Pa decays (negative beta decay)  to 233U. Therefore, proposed reactor designs must attempt to physically isolate the protactinium from further neutron capture before beta decay can occur.

## Characteristics of Thorium Reactor – Properties of Thorium

Characteristics of Thorium Reactor – Properties of Thorium

• Abundance of Natural Thorium. Although the uranium resources may be very large, it is recognized that the thorium content of the earth’s crust (0.0006% vs. 0.00018%) is about three times larger, reflecting its longer half-life. On the other hand, due to the low demand for thorium, the known reserves for uranium and thorium are both nearly identical.
• Neutronic and Thermal Parameters. For a thermal neutron spectrum (E < 1 eV) and the thorium-based fuel, the reproduction factor is considerably larger than for uranium-based fuel. Due to very low capture-to-fission ratio, the reproduction factor for uranium 233 is about η = 2.25. From this point of view is thorium fuel cycle is very promising. Another advantage can be favorable physical and chemical properties of thorium dioxide. Compared to the predominant reactor fuel, uranium dioxide (UO2), thorium dioxide (ThO2) has a higher melting point, higher thermal conductivity, and lower coefficient of thermal expansion. In particular the thermal conductivity is important, since it leads to a lower fuel pellets temperature.
• Lower Production of Transuranic Elements. The transuranics elements (plutonium and other minor actinides) are the major health concern of long-term (on the order of roughly 103 to 106 years) nuclear waste. In uranium-based fuels, only a single neutron capture in uranium 238 is sufficient to produce these transuranic elements, whereas five captures are generally necessary to do so from thorium 232. Therefore, thorium is a potentially attractive alternative to uranium-based fuels, because the production of transuranic elements is significantly lower.
• Proliferation Resistance. With regard to proliferation significance, thorium-based fuels are generally accepted as proliferation resistant compared to uranium-based fuels. This comes mostly from the fact that almost no plutonium is produced. In fact, if plutonium is used as the fissile component of thorium fuel, the plutonium is efficiently consumed. Moreover, the uranium 233 produced in thorium fuels is significantly contaminated with uranium 232 in proposed power reactor designs. 232U has a relatively short half-life of 68.9 years, and therefore the specific activity of 232U is much higher than specific activity of the isotope 238U. In addition the decay chain of 232U produces very penetrating gamma rays. The most important gamma emitter, accounting for about 85 percent of the total dose from 232U after 2 years, is thallium 208, that emits gamma rays of 2.6 MeV which are very energetic and highly penetrating. These intense radiations make handling of fissile 233U or reprocessed uranium contaminated with 232U far more dangerous than conventional fuels.
• Material Buckling. As was written, naturally occurring thorium is effectively mononuclidic of thorium 232, which is a fertile isotope. Therefore to initial fuel load another fissile material must be added to achieve criticality. This fact must be taken into account during considerations about possible advantages.
• Half-life of 233Pa. Thorium 232 is “only” a fertile material and the main problem can be directly in the breeding of fissile uranium 233. If 232Th is loaded in the nuclear reactor, the nuclei of 232Th absorb a neutron and become nuclei of 233Th. The half-life of 233Th is approximately 21.8 minutes. 233Th decays (negative beta decay) to 233Pa (protactinium), whose half-life is 26.97 days. 233Pa decays (negative beta decay)  to 233U. Therefore, proposed reactor designs must attempt to physically isolate the protactinium from further neutron capture before beta decay can occur. 233Pa is a significant neutron absorber and, although it eventually breeds into fissile 235U, this requires two more neutron absorptions, which degrades neutron economy and increases the likelihood of transuranic production.
• Radiation Protection. 232U is produced from 232Th via specific (n,2n) reactions in which an incoming neutron knocks two neutrons out of a target nucleus. 232U has a relatively short half-life of 68.9 years, and therefore the specific activity of 232U is much higher than specific activity of the isotope 238U. In addition the decay chain of 232U produces very penetrating gamma rays. These gamma rays are very hard to shield, requiring more expensive spent fuel handling and/or reprocessing.
• Delayed Neutrons. Another important aspect for reactor safety is the delayed neutron fraction. Despite the fact the number of delayed neutrons per fission neutron is quite small (typically below 1%) and thus does not contribute significantly to the power generation, they play a crucial role in the reactor control and are essential from the point of view of reactor kinetics and reactor safety. The delayed neutron fraction is significantly lower for uranium 233 than for uranium 235. In result, a reactor in which uranium 233 is the predominant isotope responds more rapidly and puts increased demands on the design of control system.

## What is Thorium

Thorium is a naturally-occurring chemical element with atomic number 90 which means there are 90 protons and 90 electrons in the atomic structure. The chemical symbol for thorium is Th. Thorium was discovered in 1828 by norwegian mineralogist Morten Thrane Esmark. Joens Jakob Berzelius, the swedish chemist, named it after Thor, the Norse god of thunder.

Thorium  is a naturally-occurring element and it is estimated to be about three times more abundant than uranium. Thorium is commonly found in monazite sands (rare earth metals containing phosphate mineral).

Thorium has 6 naturally occurring isotopes. All of these isotopes are unstable (radioactive), but only 232Th is relatively stable with half-life of 14 billion years, which is comparable to the age of the Earth (~4.5×109 years). Isotope 232Th belongs to primordial nuclides and natural thorium consists primarily of isotope 232Th. Other isotopes (230Th, 229Th, 228Th, 234Th and 227Th) occur in nature as trace radioisotopes, which originate from decay of 232Th, 235U and 238U.

## Thorium 232

Thorium 232, which alone makes up nearly all natural thorium, is the most common isotope of thorium in the nature. This isotope has the longest half-life (1.4 x 1010 years) of all isotopes with more than 83 protons. In fact, its half-life is considerably longer than the age of earth. Therefore 232Th belongs to primordial nuclides.

232Th decays via alpha decay into 228Ra . 232Th  occasionally decays by spontaneous fission with very low probability of 1.1 x 10-9 %.

232Th is a fertile isotope. 232Th is not capable of undergoing fission reaction after absorbing thermal neutron, on the other hand 232Th can be fissioned by fast neutron with energy higher than >1MeV. 232Th does not meet also alternative requirement to fissile materials. 232Th is not capable of sustaining a nuclear fission chain reaction, because too many of neutrons produced by fission of 232Th have lower energies than original neutron.

Isotope 232Th is key material in the thorium fuel cycle. Radiative capture of a neutron leads to the formation of fissile 233U. This process is called nuclear fuel breeding.

Uranium 233 breeding

232Th is the predominant isotope of natural thorium. If this fertile material is loaded in the nuclear reactor, the nuclei of 232Th absorb a neutron and become nuclei of 233Th. The half-life of 233Th is approximately 21.8 minutes. 233Th decays (negative beta decay) to 233Pa (protactinium), whose half-life is 26.97 days. 233Pa decays (negative beta decay)  to 233U, that is very good fissile material. On the other hand proposed reactor designs must attempt to physically isolate the protactinium from further neutron capture before beta decay can occur.

Thorium Reactors