Pauli Exclusion Principle

Pauli Exclusion Principle

The Pauli exclusion principle is the principle, formulated by Wolfgang Pauli in 1925, which states that:

No two electrons can occupy the same quantum-mechanical state within a given quantum system simultaneously.

In terms of the quantum numbers:

No two electrons in an atom can have the same values of all four quantum numbers.

It is impossible for two electrons of a multielectron atom to have the same values of the four quantum numbers:

  • n – the principal quantum number,
  • ℓ –  the angular momentum quantum number
  • m – the magnetic quantum number,
  • ms – the spin quantum number.

Mathematically this means the wavefunctions of the two particles must be antisymmetric which leads to the the probability amplitude of the wavefunction going to zero if the two fermionic particles are the same.

Pauli Exclusion PrincipleIt is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.

It must be noted, chemical properties of atoms are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics as well as the Pauli exclusion principle. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. As such, without the Pauli exclusion principle, there would be no chemistry.

This principle must be considered for any particles whose spin quantum number s is not zero or an integer. Therefore, this principle applies not only to electrons but also to protons and neutrons, all of which have half-integer spin.

Pauli Exclusion Principle and Nuclear Stability

Nuclide chart - Nuclear Stability
Segre chart – This chart shows a plot of the known nuclides as a function of their atomic and neutron numbers. It can be observed from the chart that there are more neutrons than protons in nuclides with Z greater than about 20 (Calcium). These extra neutrons are necessary for stability of the heavier nuclei. The excess neutrons act somewhat like nuclear glue.

Atomic nuclei consist of protons and neutrons, which attract each other through the nuclear force, while protons repel each other via the electromagnetic force due to their positive charge. These two forces compete, leading to various stability of nuclei. There are only certain combinations of neutrons and protons, which forms stable nuclei. Neutrons stabilize the nucleus, because they attract each other and protons , which helps offset the electrical repulsion between protons. As a result, as the number of protons increases, an increasing ratio of neutrons to protons is needed to form a stable nucleus. If there are too many (neutrons also obey the Pauli exclusion principle) or too few neutrons for a given number of protons, the resulting nucleus is not stable and it undergoes radioactive decay. Unstable isotopes decay through various radioactive decay pathways, most commonly alpha decay, beta decay, or electron capture. Many other rare types of decay, such as spontaneous fission or neutron emission are known.

The Pauli exclusion principle also influences the critical energy of fissile and fissionable nuclei. For example, actinides with odd neutron number are usually fissile (fissionable with slow neutrons) while actinides with even neutron number are usually not fissile (but are fissionable with fast neutrons). Heavy nuclei with an even number of protons and an even number of neutrons are (due to Pauli exclusion principle) very stable thanks to the occurrence of ‘paired spin’. On the other hand, nuclei with an odd number of protons and neutrons are mostly unstable.

Pauli Exclusion Principle and Neutron Stars

A neutron star is the collapsed core of a large star (usually of a red giant). Neutron stars are the smallest and densest stars known to exist and they are rotating extremely rapidly. A neutron star is basically a giant atomic nucleus about 11 km in diameter made especially of neutrons. It is believed that under the immense pressures of a collapsing massive stars going supernova it is possible for the electrons and protons  to combine to form neutrons via electron capture, releasing a huge amount of neutrinos. Since they have some similar properties as atomic nuclei, neutron stars are sometimes described as giant nuclei. But be careful, neutron stars and atomic nuclei are held together by different forces.  A nucleus is held together by the strong force, while a neutron star is held together by gravitational force.

On the other hand, neutron stars are partially supported against further collapse by neutron degeneracy (via degeneracy pressure), a phenomenon described by the Pauli exclusion principle. In general, in a highly dense state of matter, where gravitational pressure is extreme, quantum mechanical effects are significant. Degenerate matter is usually modelled as an ideal Fermi gas, in which the Pauli exclusion principle prevents identical fermions from occupying the same quantum state. Similarly, white dwarfs are supported against collapse by electron degeneracy pressure, which is analogous to neutron degeneracy.

References:
Nuclear and Reactor Physics:
  1. J. R. Lamarsh, Introduction to Nuclear Reactor Theory, 2nd ed., Addison-Wesley, Reading, MA (1983).
  2. J. R. Lamarsh, A. J. Baratta, Introduction to Nuclear Engineering, 3d ed., Prentice-Hall, 2001, ISBN: 0-201-82498-1.
  3. W. M. Stacey, Nuclear Reactor Physics, John Wiley & Sons, 2001, ISBN: 0- 471-39127-1.
  4. Glasstone, Sesonske. Nuclear Reactor Engineering: Reactor Systems Engineering, Springer; 4th edition, 1994, ISBN: 978-0412985317
  5. W.S.C. Williams. Nuclear and Particle Physics. Clarendon Press; 1 edition, 1991, ISBN: 978-0198520467
  6. G.R.Keepin. Physics of Nuclear Kinetics. Addison-Wesley Pub. Co; 1st edition, 1965
  7. Robert Reed Burn, Introduction to Nuclear Reactor Operation, 1988.
  8. U.S. Department of Energy, Nuclear Physics and Reactor Theory. DOE Fundamentals Handbook, Volume 1 and 2. January 1993.
  9. Paul Reuss, Neutron Physics. EDP Sciences, 2008. ISBN: 978-2759800414.

Advanced Reactor Physics:

  1. K. O. Ott, W. A. Bezella, Introductory Nuclear Reactor Statics, American Nuclear Society, Revised edition (1989), 1989, ISBN: 0-894-48033-2.
  2. K. O. Ott, R. J. Neuhold, Introductory Nuclear Reactor Dynamics, American Nuclear Society, 1985, ISBN: 0-894-48029-4.
  3. D. L. Hetrick, Dynamics of Nuclear Reactors, American Nuclear Society, 1993, ISBN: 0-894-48453-2. 
  4. E. E. Lewis, W. F. Miller, Computational Methods of Neutron Transport, American Nuclear Society, 1993, ISBN: 0-894-48452-4.

See above:

Atomic Theory