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## Moderator Temperature Coefficient

The moderator temperature coefficient – MTC is defined as the change in reactivity per degree change in moderator temperature.

α_{M} = ^{dρ}⁄_{dT}_{M}

It is expressed in units of pcm/°C or pcm/°F. The value of moderator temperature coefficient usually ranges from 0 pcm/°C to -80 pcm/°C. The magnitude and sign (+ or -) of the **moderator temperature coefficient** is primarily a function of the **moderator-to-fuel ratio**. That means it primarily depends on certain reactor design. It must be noted, according to the design requirements (e.g. NUREG-0800, Chapter 4), reactor design must assure that:

*“The MTC should be non-positive over the entire fuel cycle when the reactor is at a significant power level.”*

Therefore all light water reactors (LWR) must be designed **under moderated**, because it ensures, that the reactor may have a **negative moderator temperature coefficient**. If a reactor is over moderated, it can not reach a positive moderator temperature coefficient. A negative moderator temperature coefficient is desirable because of its **self-regulating effect**.

The total amount of reactivity, which is inserted to a reactor core by a specific change in the moderator temperature, is usually known as the **moderator reactivity defect** and is defined as:

dρ = α . dT

## Theory of Moderator Temperature Coefficient

It is very difficult to describe physics of the moderator temperatorure coefficient, because changes in **moderator temperature** lead to the change of almost **all the parameters** in a reactor core. For better understanding we describe major physical mechanisms that occur in case of **the moderator temperature coefficient** in terms of six factor formula.

**↑T _{M} ⇒ ↓k_{eff} = η.ε. ↓p . ↑f . ↓P_{f }. ↓P_{t } (BOC)**

**↑T _{M} ⇒ ↓k_{eff} = η.ε. ↓p .f. ↓P_{f }. ↓P_{t } (EOC)**

**Major impacts** on multiplication of the system arise from the change of the resonance escape probability and the change of total neutron leakage (see thermal non-leakage probability and fast non-leakage probability). But as can be seen at the beginning of the cycle (BOC), when the PWR core contains large amount boron disolved in primary coolant (chemical shim), an increase in temperature causes an increase in the thermal utilization factor.

**Change of the resonance escape probability.**It is known,**the resonance escape probability**is dependent also on the**moderator-to-fuel ratio**. All PWRs are designed as undermoderated reactors. As the**moderator temperature**increases the ratio of the moderating atoms (molecules of water) decreases as a result of the**thermal expansion of water**. Its density simply decreases. This, in turn, causes a**hardening of neutron spectrum**in the reactor core resulting in**higher resonance absorption**(lower p). Decreasing density of the moderator causes that neutrons stay at a higher energy for a longer period, which increases the probability of non-fission capture of these neutrons. It must be added moderator density changes are not linear. At high temperatures an increase in the moderator temperature causes a larger reduction in density than an identical increase at low moderator temperatures. This process (the**hardening of neutron spectrum**) is one of two key processes, which determine the**moderator temperature coefficient (MTC)**. The second process is connected with the leakage probability of the neutrons.

**Change of the neutron leakage.**Since both (**P**) are affected by a change in_{f}and P_{t}**moderator temperature**in a heterogeneous water-moderated reactor and the directions of the feedbacks is the same, the resulting**total non-leakage probability**is also sensitive on the change in the moderator temperature. In result, an**increase in the moderator temperature**causes that the probability of**leakage increases**. In case of**the fast neutron leakage,**the moderator temperature influences macroscopic cross-sections for elastic scattering reaction (Σ_{s}=σ_{s}.N_{H}_{2}O) due to the**thermal expansion of water**, which results in an increase in the**moderation length**. This, in turn, causes an increase of the leakage of fast neutrons.- For
**the thermal neutron leakage**there are two effects. Both processes have the same direction and together causes the increase in the thermal neutron leakage. This physical process is a part of the**moderator temperature coefficient (MTC).**- Macroscopic cross-sections for elastic scattering reaction
**Σ**which significantly changes due to the_{s}=σ_{s}.N_{H}_{2}O,**thermal expansion**of water. As the temperature of the core increases,**the diffusion coefficient**(**D = 1/3.Σ**) increases._{tr} - Microscopic cross-section (
**σ**) for neutron absorption changes with core temperature. As the temperature of the core increases, the absorption cross-section decreases._{a}

- Macroscopic cross-sections for elastic scattering reaction

- For

**Change of the thermal utilization factor.**The impact on the thermal utilization factor depends strongly on the amount of boron which is diluted in the primary coolant (chemical shim).**thermal expansion**of water. But along with the moderator also**boric acid is expanded**out of the core. Since boric acid is a neutron poison, and it is expanding out of the core, positive reactivity is added. The positive reactivity addition due to the expansion of boron out of the core offsets the negative reactivity addition due to the expansion of the moderator out of the core. The resulting MTC is therefore strongly dependent on the concentration of boron in primary coolant. It is obvious this effect is significant**at the beginning of the cycle**(BOC) and gradually loses its significance as the boron concentration decreases. In case of PWRs, burnable poisons are usually used to reduce the amount of dissolved boron. Without**burnable absorbers**it would be impossible to reach non-positive MTC, especially today, when utilities are demanding the vendors to design cores that can operate from 18 to 24 months at full power. In PWRs, samarium concentration can also influence the MTC at BOC. Note that, the**samarium peak concentration**after shutdown,**is flux dependent!**Sudden shutdown of a reactor at the end of the cycle lowers MTC (lowers critical boron concentration) at the beginning of the next cycle.

## Moderator Temperature Coefficient and Reactor Design

As was written, the **moderator temperature coefficient** is primarily a function of the **moderator-to-fuel ratio **(**N _{H2O}/N_{Fuel} ratio**). The

**moderator-to-fuel ratio**is the ratio of the number of moderator nuclei within the volume of a reactor core to the number of fuel nuclei. As the core temperature increases, fuel volume and number density remain essentially constant. The volume of moderator also remains constant, but the number density of moderator decreases with

**thermal expansion**. As the

**moderator temperature**increases the ratio of the moderating atoms (molecules of water) decreases as a result of the

**thermal expansion of water**(especially at 300°C; see: Density of Water). Its density simply and significantly decreases. This, in turn, causes a

**hardening of neutron spectrum**in the reactor core resulting in

**higher resonance absorption**(lower p). Decreasing density of the moderator causes that neutrons stay at a higher energy for a longer period, which increases the probability of non-fission capture of these neutrons. This process is one of three processes, which determine the

**moderator temperature coefficient (MTC)**. The second process is associated with the leakage probability of the neutrons and the third with the

**thermal utilization factor**.

**The moderator-to-fuel ratio **strongly influences especially:

**Resonance escape probability.**An increase in**moderator-to-fuel ratio causes**an increase in resonance escape probability. As more moderator molecules are added relative to the amount of fuel molecules, than it becomes easy for neutrons to slow down to thermal energies without encountering a resonance absorption at the resonance energies.**Thermal utilization factor.**An increase in**moderator-to-fuel ratio causes**a decrease in thermal utilization factor. The value of**the thermal utilization factor**is given by the ratio of the number of thermal neutrons absorbed in the fuel (**all nuclides**) to the number of thermal neutrons absorbed in**all the material**that makes up the core.- Thermal and fast non-leakage probability. An increase in
**moderator-to-fuel ratio causes**a decrease in migration length, which in turn causes an increase in non-leakage probability.

As can be seen from the figure, at low **moderator-to-fuel ratios **the product of all the six factors (k_{eff}) is small because the resonance escape probability is small. At optimal value of **moderator-to-fuel ratio, **k_{eff} reaches its maximum value. This is the case of so called “optimal moderation”. At large ratios, k_{eff} is again small because **the thermal utilization factor** is small.

**Under-moderated vs. Over-moderated Reactor**

From the **moderator-to-fuel ratio** point of view, any multiplying system can be designed as:

**Under-moderated**. Under-moderation means that there is**less than optimum**amount of**moderator**between fuel plates or fuel rods. An increase in moderator temperature and voids decreases k_{eff}of the system and inserts negative reactivity. An under-moderated core would create a negative temperature and void feedback required for a**stable system**.

**Over-moderated**. Over-moderation means that there is**higher than optimum**amount of**moderator**between fuel plates or fuel rods. An increase in moderator temperature and voids increases k_{eff}of the system and inserts positive reactivity. An over-moderated core would create a positive temperature and void feedback. It will result in an**unstable system**, unless another negative feedback mechanism (e.g. the Doppler broadening) overrides the positive effect.

Reactor engineers must balance the composite effects of moderator density, fuel temperature, and other phenomena to ensure system stability under all operating conditions. Most of light water reactors are therefore designed as so called **under-moderated** and the **neutron flux spectrum** is slightly **harder** (the moderation is slightly insufficient) than in an optimum case. But this design provides important safety feature. An increase in the moderator temperature results in negative reactivity which tends to make the reactor **self-regulating**. It must be added, the overall feedback must be negative, but** local positive coefficients** exists in areas with **large water gaps** that are over-moderated such as near control rods guide tubes.

Another phenomenon associated with under-moderated core is called the **neutron flux trap effect**. This effect causes an increase in local power generation due better thermalisation of neutrons in areas with large water gaps (between fuel assemblies or when fuel assembly bow phenomenon is present). Note that “flux traps” are a standard feature of most modern test reactors because of the desire to obtain high thermal neutron fluxes for the irradiation of materials, but basically it can occur also in PWRs.

On the other hand, also **under-moderation** has its **limits**. In general, it causes a decrease in overall k_{eff}, therefore more fissile material is needed to ensure criticality of the core. Moreover, there is also a limit on the minimal value of MTC (most negative). It is due to the fact the negative temperature feedback acts also against decrease in the moderator temperature. Consider what happens when moderator temperature is decreased **quickly**, as in the case of the **main steamline break** (MSLB – standard initiating event for PWRs). The steamline break causes the steam pressure, the saturation temperature in the steam generators to fall rapidly. As a result of falling saturation temperature in the steam generators the **moderator temperature** will rapidly decrease. The rapid moderator temperature drop causes a positive reactivity insertion. The amount of reactivity inserted depends also on a magnitude of the MTC and therefore it must be limited. Typical values for lower limit is MTC = -80 pcm/°C, but it is a plant specific value limited in technical specifications.