Neutron Poisons – Reactor Poisoning

Neutron Poisons – Reactor Poisoning

Fission fragment yields
Fission fragment yield for different nuclei. The most probable fragment masses are around mass 95 (Krypton) and 137 (Barium).

Nuclear fission fragments are the fragments left after a nucleus fissions. The average of the fragment mass is about 118, but very few fragments near that average are found. It is much more probable to break up into unequal fragments, and the most probable fragment masses are around mass 95 (Krypton) and 137 (Barium). Most of these fission fragments are highly unstable (radioactive) and undergo further radioactive decays to stabilize itself.

Plenty of isotopes, usually neutron rich isotopes, are produced by fission. Many of the resulting fission products have measurable thermal absorption cross sections. Fission products are of concern in reactors primarily because they become parasitic absorbers of neutrons and result in long term sources of heat (so called decay heat). Their buildup in the reactor tends to reduce the multiplication factor. For that reason, these nuclei are known as neutron poisons.

The significance of each poison depends both on the yield, decay rates and its absorption cross-section. During reactor operation equilibrium is eventually reached if a radioisotope is produced at a constant rate, for after several half-lives the rate of decay will equal the rate of production. Most fission products have low absorption cross-section, but there are very important exceptions. These isotopes are described in the following table.

Table of Neutron Poisons

As can be seen, most of these isotopes are stable and some undergo a decay. From this point of view, we distinguish between neutron poisons, which causes reactor poisoning and neutron poisons, which causes reactor slagging.

The isotope with short half-life (e.g. xenon-135) is known as reactor poison, while the isotope that is long-lived or even stable is known as reactor slag. The neutron absorbing fission products xenon-135 and samarium-149 have particular operational importance.

Their concentrations can change quickly, producing major changes in neutron absorption on a relatively short time scale. Because these two fission product poisons remove neutrons from the reactor, they will have an impact on the thermal utilization factor and thus keff and reactivity. Importance of xenon-135 and samarium-149 is so high, that it will be discussed in separate section.

It must be noted, neutron-absorbing materials, also called neutron poisons, are intentionally inserted into some types of reactors in order to lower the high reactivity of their initial fresh fuel load. Some of these poisons deplete as they absorb neutrons during reactor operation, while others remain relatively constant.

Reactor Slagging – Reactor Slag

As was written, an isotope that is long-lived or even stable is known as reactor slag. The accumulation of these parasitic absorbers is known as reactor slagging and determines the lifetime of nuclear fuel in a reactor, since their buildup causes (together with a decrease in fissile material) continuous decrease in core reactivity.

Table of Neutron PoisonsSamarium 149 belongs to this group of isotopes, but its importance is so high, that it is usually discussed separately. As can be seen from the table, there are numerous other fission products that, as a result of their concentration and thermal neutron absorption cross section, have a poisoning effect on reactor operation. Other fission products with relatively high absorption cross sections include 83Kr, 95Mo, 143Nd, 147Pm. Individually, they are of little consequence, but taken together they have a significant effect. These are often characterized as lumped fission product poisons.

As was written, for fuel burnup of 40 GWd/tU, approximately 3 – 4% of the heavy nuclei are fissioned. The discharged fuel (spent nuclear fuel) still contains about 96% of reusable material. It must be removed due to decreasing kinf of an assembly or in or in other words, it must be removed due to:

  • accumulation of fission products with significant absorption cross-section.
  • decrease in fissile material

This is the reason, why some nuclear power plant operators use reprocessed fuel to partially replace fresh uranium fuel. Nuclear reprocessing is technology that was developed to chemically separate and recover fissionable material from spent nuclear fuel as well as to remove these isotopes with significant absorption cross-section.

 
References:
Nuclear and Reactor Physics:
  1. J. R. Lamarsh, Introduction to Nuclear Reactor Theory, 2nd ed., Addison-Wesley, Reading, MA (1983).
  2. J. R. Lamarsh, A. J. Baratta, Introduction to Nuclear Engineering, 3d ed., Prentice-Hall, 2001, ISBN: 0-201-82498-1.
  3. W. M. Stacey, Nuclear Reactor Physics, John Wiley & Sons, 2001, ISBN: 0- 471-39127-1.
  4. Glasstone, Sesonske. Nuclear Reactor Engineering: Reactor Systems Engineering, Springer; 4th edition, 1994, ISBN: 978-0412985317
  5. W.S.C. Williams. Nuclear and Particle Physics. Clarendon Press; 1 edition, 1991, ISBN: 978-0198520467
  6. G.R.Keepin. Physics of Nuclear Kinetics. Addison-Wesley Pub. Co; 1st edition, 1965
  7. Robert Reed Burn, Introduction to Nuclear Reactor Operation, 1988.
  8. U.S. Department of Energy, Nuclear Physics and Reactor Theory. DOE Fundamentals Handbook, Volume 1 and 2. January 1993.

Advanced Reactor Physics:

  1. K. O. Ott, W. A. Bezella, Introductory Nuclear Reactor Statics, American Nuclear Society, Revised edition (1989), 1989, ISBN: 0-894-48033-2.
  2. K. O. Ott, R. J. Neuhold, Introductory Nuclear Reactor Dynamics, American Nuclear Society, 1985, ISBN: 0-894-48029-4.
  3. D. L. Hetrick, Dynamics of Nuclear Reactors, American Nuclear Society, 1993, ISBN: 0-894-48453-2. 
  4. E. E. Lewis, W. F. Miller, Computational Methods of Neutron Transport, American Nuclear Society, 1993, ISBN: 0-894-48452-4.

See above:

Fuel Burnup